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E-raamat: Ceramic Fibers and Their Applications

Hervé This vo Kientza (INRAE/AgroParisTech)

Formaat: EPUB+DRM
Ilmumisaeg: 31-Oct-2019
Kirjastus: Pan Stanford Publishing Pte Ltd
Keel: eng
ISBN-13: 9781000682434

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Formaat: EPUB+DRM
Ilmumisaeg: 31-Oct-2019
Kirjastus: Pan Stanford Publishing Pte Ltd
Keel: eng
ISBN-13: 9781000682434

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To date, many types of polymer-derived ceramic fibers have been developed all over the world. Of these, SiC fibers synthesized from polycarbosilane and its derivatives have achieved the highest heat-resistance along with their excellent mechanical properties. Using these type of SiC fibers for the ceramic matrix composite materials, both high-temperature strength and light weight have been achieved. Therefore, these fibers have attracted a great deal of attention in the field of next-generation aerospace engine, nuclear applications, and so on. Furthermore, several types of functional ceramic fibers with surface gradient structures have been developed using derivatives of polycarbosilane. This book summarizes the historical viewpoint of polymer-derived ceramic fibers, basic information (production process, fine structures, physical properties, and so forth) about them, and their applications. It also presents prospects of future inorganic fibers.

Preface

vii

1 Historical Viewpoint of Ceramic Fibers

(22)

1.1 Introduction

(3)

1.2 Historical Trend of Each Inorganic Fiber

(18)

1.2.1 Historical Trend of Carbon Fibers

(3)

1.2.2 Historical Trend of Oxide Fibers

(5)

1.2.3 Historical Trend of Silicon Carbide Fibers

(4)

1.2.4 Historical Trend of Silicon Carbide Derivatives

(2)

1.2.5 Historical Trend of Functional Ceramic Fibers with Surface Gradient Structures

(4)

2 Progress of Ceramic Fibers

(44)

2.1 Introduction

(1)

2.2 Polymer-Derived Si-Based Ceramic Fibers

(16)

2.2.1 SiC Fibers: From First Generation to Third Generation

(1)

2.2.1.1 Tyranno S, Lox M, ZMI, and Tyranno SA

(7)

2.2.1.2 Nicalon, Hi-Nicalon, and Hi-Nicalon Type S

(3)

2.2.1.3 Sylramic SiC fiber

(1)

2.2.2 Summary of Commercial Polymer-Derived SiC Fibers

(4)

2.3 Polymer-Derived Functional Ceramic Fibers

(16)

2.3.1 Photocatalytic Fiber (TiO2/SiO2 Fiber)

(2)

2.3.1.1 Synthesis of the TiO2/SiO2 photocatalytic fiber

(4)

2.3.1.2 Palladium-deposited mesoporous photocatalytic fiber with high photocatalytic activity

(1)

2.3.1.3 Environmental application of the TiO2/SiO2 photocatalytic fiber

(5)

2.3.2 Alkali-Resistant SiC Fiber (ZrO2/SiC Fiber)

(4)

2.4 Derivatives of Polymer-Derived Si-Based Fibers

(6)

2.4.1 Thermally Conductive, Tough Ceramic (SA-Tyrannohex) Making the Best Use of Production Process of Tyranno SA Fiber

(2)

2.4.2 Physical Properties of SA-Tyrannohex

(4)

2.5 Ceramic Matrix Composite

(6)

3 Mechanical Strength of Ceramic Fibers

(16)

3.1 Introduction

(1)

3.2 Tensile Strength and Weibull Analysis

(3)

3.3 Characterization of the Fracture Surface of Tyranno SA Fiber

(2)

3.4 Characterization of the Fracture Origin of Tyranno SA Fiber

(1)

3.5 Calculation Results and Desirable Heat-Treatment Condition for Achieving Lesser Defects

(9)

4 High-Temperature Properties of SiC-Based Ceramic Fibers

(14)

4.1 Introduction

(1)

4.2 Oxidation Resistance of Amorphous SiC-Based Fiber Aiming for Insulator Application

(9)

4.2.1 Changes in the Crystalline Structure by Oxidation

(1)

4.2.2 Changes in the Microstructure by Oxidation

(3)

4.2.3 Stable Emissivity after Oxidation

(4)

4.3 Oxidation Resistance of SiC-Polycrystalline Fiber (Tyranno SA Fiber)

(5)

Index

Toshihiro Ishikawa is vice president of Tokyo University of Science (San'y-Onoda City University), Yamaguchi, Japan. He has conducted unique and innovative works on multifunctional ceramics and composites during the past thirty years and has made outstanding contribution to the field of science and technology. He has authored or co-authored more than 150 peer-reviewed papers, including 2 for Nature and 1 for Science. Prof. Ishikawa has received several awards and prizes, including the Yamazaki Teiichi Prize, Japan (2003); GSC Award (2004); ACerS Global Ambassador Award (2019); and awards from the Minister for Environment (2004), Society of Chemical Engineers (2003), and Society of Polymer Science (1992).

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