Muutke küpsiste eelistusi

E-raamat: Combinatorial and High-Throughput Discovery and Optimization of Catalysts and Materials

  • Formaat - EPUB+DRM
  • Hind: 88,39 €*
  • * hind on lõplik, st. muud allahindlused enam ei rakendu
  • Lisa ostukorvi
  • Lisa soovinimekirja
  • See e-raamat on mõeldud ainult isiklikuks kasutamiseks. E-raamatuid ei saa tagastada.

DRM piirangud

  • Kopeerimine (copy/paste):

    ei ole lubatud

  • Printimine:

    ei ole lubatud

  • Kasutamine:

    Digitaalõiguste kaitse (DRM)
    Kirjastus on väljastanud selle e-raamatu krüpteeritud kujul, mis tähendab, et selle lugemiseks peate installeerima spetsiaalse tarkvara. Samuti peate looma endale  Adobe ID Rohkem infot siin. E-raamatut saab lugeda 1 kasutaja ning alla laadida kuni 6'de seadmesse (kõik autoriseeritud sama Adobe ID-ga).

    Vajalik tarkvara
    Mobiilsetes seadmetes (telefon või tahvelarvuti) lugemiseks peate installeerima selle tasuta rakenduse: PocketBook Reader (iOS / Android)

    PC või Mac seadmes lugemiseks peate installima Adobe Digital Editionsi (Seeon tasuta rakendus spetsiaalselt e-raamatute lugemiseks. Seda ei tohi segamini ajada Adober Reader'iga, mis tõenäoliselt on juba teie arvutisse installeeritud )

    Seda e-raamatut ei saa lugeda Amazon Kindle's. 

The development of parallel synthesis and high-throughput characterization tools offer scientists a time-efficient and cost-effective solution for accelerating traditional synthesis processes and developing the structure-property relationships of multiple materials under variable conditions. Written by renowned contributors to the field, Combinatorial and High-Throughput Discovery and Optimization of Catalysts and Materials documents the impact of combinatorial methods for inorganic, organic, polymeric, and biological materials applications over the last several years.

This valuable reference describes techniques for the preparation, formulation, fabrication, optimization, performance testing, and evaluation of catalysts, polymeric materials arrays, sensing materials, fuel cell battery and memory materials, semiconductor nanoclusters, dielectrics, OLED arrays, additives, organic coatings, luminescent materials, and phosphors. The book introduces some of the latest features in the development of combinatorial and high throughput workflows, including new library designs, the scale-up of combinatorially discovered materials, and innovative methods of data storage, data mining and informatics. It also points to active research in the development of intelligent software for data mining including multiparameter modeling and visualization.

As combinatorial materials science becomes increasingly applicable to a growing number of materials and problems, Combinatorial and High-Throughput Discovery and Optimization of Catalysts and Materials provides an essential portrait of the success, challenges, and opportunities in this field for the next generation of combinatorial chemists, material scientists, and industrial chemists and academics.
SECTION 1 General Aspects of Combinatorial Materials Science
Combinatorial Materials and Catalysts Development: Where Are We and How Far Can We Go?
3(14)
Radislav A. Potyrailo
Wilhelm F. Maier
Introduction
3(3)
Combinatorial Materials Science (Where Are We?)
6(5)
Scale-Up of Combinatorial Leads
11(1)
Remaining Challenges (How Far Can We Go?)
11(1)
Outlook
12(5)
References
13(4)
Expanding the Scope of Combinatorial Synthesis of Inorganic Solids: Application of the Split & Pool Principle for the Screening of Functional Materials
17(30)
Stephan Andreas Schunk
Peter Kolb
Andreas Sundermann
Torsten Zech
Jens Klein
Introduction
18(1)
Combinatorial Synthesis of Organic Compounds
18(6)
Pitfalls and Challenges in Organic Combinatorial Synthesis
24(2)
Methods for Monomer Linkage
24(1)
Different Types of Linkers
25(1)
Monitoring the Progress of a Reaction and Identifying the Products
25(1)
High-Throughput Synthesis of Inorganic Compounds
26(4)
Approaches Used in the Generation of Organic Compounds
26(2)
The Transition to Inorganic Materials
28(1)
Alternative Approaches: Substrate-Free Synthetic Concepts
29(1)
Applying CombiChem to Inorganic Materials: The Split&Pool Principle
30(1)
Mathematical Background for Split&Pool Synthesis
31(5)
Basic Considerations
31(2)
Challenges of Inorganic Split&Pool Synthesis
33(3)
Beyond Theoretical Considerations: Application Examples of the Combinatorial Synthesis of Functional Inorganic Materials via the Split&Pool Methodology
36(5)
Synthetic Example
38(3)
Outlook and Future
41(6)
Acknowledgments
42(1)
References
42(5)
Informatics-Based Optimization of Crystallographic Descriptors for Framework Structures
47(14)
Arun Rajagopalan
Krishna Rajan
Introduction
47(1)
Wigner--Seitz Cells and Zeolite Classification Schemes
47(2)
Wigner--Seitz Cells
47(1)
Current Zeolite Classification Schemes
48(1)
Crystallographic Enumeration Schemes
49(1)
Background
49(1)
Wigner--Seitz Cell-Based Secondary Descriptors
50(1)
Informatics Strategy
50(7)
Conclusions and Future Work
57(4)
Acknowledgments
58(1)
References
58(3)
Combinatorial Study of New Glasses
61(24)
Tomoya Konishi
Shigeru Suehara
Shin-ichi Todoroki
Satoru Inoue
Introduction
61(1)
Experimental
62(6)
Prediction of Glass-Forming Compositions
62(1)
Instrumental Details
63(1)
Automatic Batch Preparation Apparatus
63(1)
Multisample Glass-Melting Furnace
64(1)
Multisample Glass-Forming Tester
65(3)
Automatic Glass-Forming Detector
68(1)
New Glasses Discovered through a Combinatorial Method
68(12)
Reddish-Colored Glass: The P2O5-TeO2-ZnO System
68(3)
Low-Melting and Lead-Free Glass: The B2O3-TeO2-BaF2/BaO System
71(4)
Host Glass for Divalent Rare Earth: The Na2O-B2O3-SiO2:Sm2C System
75(4)
Fluorescent Glass: The WO3-P2O5-ZnO System
79(1)
Conclusion
80(5)
References
82(3)
A Combinatorial Method for Optimization of Materials for Gas-Sensitive Field-Effect Devices
85(14)
Mats Eriksson
Roger Klingvall
Ingemar Lundstrom
Introduction
85(2)
Combinatorial Method
87(3)
Gas-Sensitive Devices with Continuously Varying Properties in Two Dimensions
87(1)
Readout of the Gas Response with Lateral Resolution
88(2)
The Combinatorial Method Applied to Double Layers of Rh + Pd and Pt + Pd as Gas-Sensitive Layers
90(4)
Concluding Remarks and Perspective
94(5)
References
95(4)
SECTION 2 Catalysis: Development and Discovery
Use of Combinatorial Heat Treatments to Accelerate the Commercialization of Materials for Use in Catalysis
99(16)
Maureen Bricker
Lorenz Bauer
Michael Gatter
Jennifer Abrahamian
Ralph Gillespie
Introduction
99(1)
Catalyst Preparation Module
100(1)
Heat Treatments: An Overview
100(4)
Heat Treatment of Molecular Sieves for Acid Catalysts
101(1)
Heat Treatment of Alumina-Based Materials
101(1)
Test Design
102(1)
Using Heat Treatments for Follow-Up Studies
103(1)
The Heat Treatment Unit
104(1)
Examples of Using Parallel Heat Treatments to Solve Commercially Relevant Problems
105(6)
Case Study I: Finding the Optimum Finishing Temperature for a Prototype Catalyst Material
105(2)
Case Study II: Evaluation of 37 New Acidic Materials for Application
107(3)
Case Study III: Evaluation of Synthesis Methods to Find a More Stable Zeolite
110(1)
Conclusion
111(4)
Acknowledgments
112(1)
References
112(3)
Infrared Thermography and High-Throughput Activity Techniques for Catalyst Evaluation for Hydrogen Generation from Methanol
115(14)
Eduardo E. Wolf
Stephen Schuyten
Dong Jin Suh
Introduction
115(4)
Experimental Method and Procedure
119(1)
IRT Reactor
119(1)
Parallel Reactor
120(1)
Catalyst Preparation and Reaction
120(1)
Results and Discussion
120(4)
Model of the Ideal Catalyst
120(1)
IRT Reactor Results
120(1)
Parallel-Flow Reactor
121(2)
Single-Flow Reactor
123(1)
Conclusions
124(5)
References
125(4)
New Catalysts for the Carbonylation of Phenol: Discovery Using High-Throughput Screening and Leads Scale-Up
129(20)
Donald W. Whisenhunt, Jr.
Grigorii Soloveichik
Introduction
130(3)
Diphenylcarbonate (DPC) and the Search for a One-Step Process
130(3)
High-Throughput Catalysis Development
133(1)
Experimental
133(3)
Materials
133(1)
Analytical
134(1)
Equipment
134(1)
Small-Scale Reactions
134(2)
Batch-Scale Reactions
136(1)
Bench-Top Unit Reaction
136(1)
Results and Discussion
136(10)
Variability in Small-Vial Reactions
136(1)
Correlation with Batch-Scale Reactions
137(1)
Identification of New Co-Catalysts
137(1)
Optimization of the Pb/Ti System
138(1)
Addition of Base and Variation Process Parameters
139(1)
Optimization of the Pb/Ti/Base System Batch Scale
139(3)
Bench-Top Unit Performance of Top Systems
142(2)
Mechanism of DPC Formation
144(2)
Conclusions
146(3)
Acknowledgments
146(1)
References
146(3)
Catalyst Preparation for Parallel Testing in Heterogeneous Catalysis
149(24)
Sabine Schimpf
Martin Lucas
Peter Claus
Introduction
149(1)
Catalyst Preparation for Primary Screening (Discovery Stage)
150(7)
Thin-Film Deposition-Based Catalyst Preparation Methods for Heterogeneous Catalysis
150(1)
Solution-Based Catalyst Preparation Methods for Heterogeneous Catalysis
151(1)
Impregnation Methods
152(3)
Precipitation Methods
155(1)
Precipitation and Co-Precipitation
155(1)
Sol--Gel Method
156(1)
Hydrothermal Synthesis of Zeolites
156(1)
Multinary Oxides by Using Activated Carbon as an Exotemplate
157(1)
Catalyst Preparation for Catalytically Coated Reactors
157(5)
Catalyst Preparation in Monolith Structures
157(2)
Microchannel Reactors
159(3)
Preparation Techniques for Secondary Screening (Optimization Stage)
162(6)
Fixed-Bed Reactors
162(2)
Reactors for Liquid Phase/Multiphase Reactions
164(4)
Summary
168(5)
References
168(5)
Tailoring Heterogeneous Catalysts for Pollutant Combustion with High-throughput Methods
173(22)
Timm Schmidt
Gerald Frenzer
Wilhelm F. Maier
Introduction
174(2)
Experimental Part
176(3)
Mixed-Oxide Syntheses
176(1)
Synthesis 1
176(1)
Synthesis 2
176(1)
Synthesis 3
176(1)
Synthesis 4
177(1)
Synthesis 5
177(1)
Synthesis of Mixed Metal Oxides Applied for the Conventional Experiments
177(1)
High-Throughput Screening
177(1)
Experiments in the Plug-Flow Reactor
177(1)
Combustion of DMEA
178(1)
Combustion of DMEA
178(1)
Combustion of DMEA
178(1)
Combustion of Benzene
179(1)
Sequential Combustion of Benzene-, DMEA and DMDS
179(1)
Simultaneous Combustion of DMEA and DMDS
179(1)
Results and Discussion
179(11)
High-Throughput Screening
179(1)
Dimethylethyl Amine (DMEA)
180(4)
Benzene
184(1)
Dimethyl Disulfide (DMDS)
185(1)
Conventional Confirmation of Catalytic Activity
186(1)
Dimethylethyl Amine (DMEA)
186(1)
Benzene
187(2)
Sequential and Simultaneous Combustion of DMEA, DMDS, and Benzene
189(1)
Summary and Conclusions
190(5)
Acknowledgment
191(1)
References
191(4)
SECTION 3 Development of Functional Polymers
One-Dimensional Polymeric Formulated Materials Arrays: Fabrication, High-Throughput Performance Testing, and Applications
195(26)
Radislav A. Potyrailo
Ronald J. Wroczynski
Introduction
195(1)
Concept of Integrated Microextrusion and High-Throughput Performance Testing of One-Dimensional Polymeric Materials
196(3)
Experimental Methodologies
199(2)
Combinatorial Microextruder System
199(1)
High-Throughput Fluorescence Analysis
200(1)
Performance Testing
201(1)
Data Analysis and Mining
201(1)
Case Studies
201(16)
Fluorescence as HT Detection Method of Process Degradation of Polymers
201(3)
In-Line Monitoring
204(4)
Analysis of Coiled One-Dimensional Arrays
208(4)
Evaluation of Weathering
212(5)
Summary
217(4)
Acknowledgment
217(1)
References
217(4)
A Combinatorial Approach to Rapid Structure Property Screening of UV-Curable Cycloaliphatic Epoxies
221(18)
Fawn M. Uhl
Christine M. Gallagher-Lein
David A. Christianson
James A. Bahr
Bret J. Chisholm
Nathan J. Gubbins
Dean C. Webster
Introduction
221(1)
Experimental
222(3)
Materials
222(1)
Formulations
222(2)
Instrumentation
224(1)
Results and Discussion
225(12)
Differential Scanning Calorimetry (DSC)
226(1)
Dynamic Mechanical Thermal Analysis (DMTA)
226(6)
Thermogravimetric Analysis (TGA)
232(2)
Contact Angle and Surface Energy (Interfacial Tension)
234(1)
Adhesion
235(2)
Conclusions
237(2)
Acknowledgments
237(1)
References
237(2)
Combinatorial Synthesis and Screening of Photochromic Dyes and Modified Conducting Polymers
239(20)
Diego F. Acevedo
Maria C. Miras
Cesar A. Barbero
Introduction
239(2)
Results and Discussion
241(9)
Photochromic Dyes
241(1)
Combinatorial Synthesis
241(1)
High-Throughput Screening (HTS) of Photochromic Dyes
242(1)
Modified Conducting Polymers
243(2)
Combinatorial Synthesis of Diazonium Ions
245(1)
Solubility of Conducting Polymers
245(3)
Measurement of Polymer Conductivity
248(1)
Structure--Property Relationships in the Polymer Library
248(1)
Photochromic Conducting Polymers
248(2)
Conclusions
250(1)
Experimental
251(8)
Polymer Synthesis
251(1)
Dye Synthesis
251(1)
Polyaniline Modification
251(1)
Solubility Measurements
252(1)
Conductivity Measurements
252(1)
FTIR Spectroscopy
252(1)
UV -- Visible Absorption Spectroscopy
252(1)
UV -- Visible Emission (Fluorescence) Spectroscopy
252(1)
Acknowledgments
252(1)
References
252(7)
SECTION 4 Energy-Related Materials Development
High-Throughput Screening for Fuel Cell Technology
259(20)
Jing Hua Liu
Min Ku Jeon
Asif Mahmood
Seong Ihl Woo
Introduction
259(1)
Optical Screening
260(4)
Electrochemical Screening
264(7)
Scanning Electrochemical Microscopy
271(1)
IR Thermography Screening
272(1)
Conclusion
273(6)
Acknowledgments
273(4)
References
277(2)
High-Throughput Discovery of Battery Materials
279(26)
Alan D. Spong
Girts Vitins
John R. Owen
Introduction: Figures of Merit
279(1)
Charge Capacity and Its Reversibility
280(1)
Active Potential Range
281(2)
Specific Energy and Power
283(1)
Performance, Cyclability, and Life
283(1)
Combinatorial Synthesis of Cell Materials
284(5)
Physical Vapor Deposition (PVD)
284(1)
Electrodeposition
285(2)
Sol--Gel Synthesis
287(1)
Paste Deposition of Thick Electrode Films
288(1)
Electrolyte Synthesis
289(1)
High-Throughput Electrochemical Characterization
289(4)
Galvanostatic Cycling
289(1)
Cyclic Voltammetry
290(3)
Conductivity Measurements and Complex Impedance Spectroscopy
293(1)
Results
293(6)
Thin Films of Metal Alloys and Oxides
293(1)
Percolation Effects in Thick Films of Composite-Positive Electrodes
293(3)
Electronic Conductivity
296(1)
Sol--Gel Syntheses
296(3)
Conclusions and Future Prospects
299(6)
References
299(6)
SECTION 5 Electronic Materials Development
Innovation in Magnetic Data Storage Using Physical Deposition and Combinatorial Methods
305(18)
Erik B. Svedberg
Introduction
305(1)
Methodology
305(8)
Example
310(3)
Models
313(7)
Summary
320(3)
References
320(3)
High-Throughput Screening of Next Generation Memory Materials
323(14)
Chang Hwa Jung
Eun Jung Sun
Seong Ihl Woo
Introduction
323(1)
Dynamic/Ferroelectric Random Access Memory (DRAM/FRAM)
324(3)
DRAM
324(1)
FRAM
324(3)
Phase Change Random Access Memory (PRAM)
327(3)
Introduction
327(2)
Combinatorial Method for PRAM
329(1)
Magnetoresistive Random Access Memory (MRAM)
330(3)
Introduction
330(2)
Combinatorial Method for MRAM
332(1)
Conclusion
333(4)
References
334(3)
Combinatorial Ion Beam Synthesis of II--VI Compound Semiconductor Nanoclusters
337(24)
Helmut Karl
Introduction
337(4)
Combinatorial Ion Implantation
341(1)
High-Dose Ion Implantation
342(9)
Compound Formation and Phase Separation
342(3)
Particle Distribution: Self-Organization
345(3)
Measurement of Particle Size, Distribution, and Interparticle Distance
348(1)
Cross-Sectional Transmission Electron Microscopy (XTEM)
348(1)
X-Ray Diffraction (XRD)
348(1)
Grazing Incidence Small-Angle X-Ray Scattering (GISAXS)
349(1)
Phase Analysis
349(2)
Photoluminescence
351(6)
Summary and Outlook
357(4)
References
358(3)
Preparation of Dielectric Thin-Film Libraries by Sol--Gel Techniques
361(18)
Virginie Jehanno
Berit Wessler
Wolfgang Rossner
Gerald Frenzer
Wilhelm F. Maier
Introduction
361(1)
Library Synthesis
362(11)
Precursor Set
362(1)
Synthesis Techniques
362(1)
Binary and Ternary Combinations of the Single-Element Precursors
363(1)
Prestructuring of the Substrates
363(2)
Deposition of the Samples
365(1)
Characterization of the Thin Films
366(1)
Elemental Composition
366(3)
Determination of Film Properties
369(2)
Phase Composition
371(2)
Discussion on High-Throughput Characterizations
373(1)
Conclusion
374(5)
References
374(5)
SECTION 6 Optic Materials
Combinatorial Fabrication and Screening of Organic Light-Emitting Device Arrays
379(26)
Joseph Shinar
Gang Li
Kwang Ohk Cheon
Zhaoqun Zhou
Ruth Shinar
Introduction
380(1)
Combinatorial Screening of Luminescent Materials
380(1)
Combinatorial Screening of Electron and Hole Transport Layers
380(1)
Combinatorial Screening of Doping in OLEDs
381(1)
Case Study
1. Two-Dimensional Combinatorial Fabrication and Screening of UV-Violet OLEDs
382(4)
Introduction
382(1)
Experimental Procedure
382(1)
ITO/CuPc/CBP/Bu-PBD/[ CsF or A1Ox]/A1 OLEDs
382(2)
ITO/CuPc/CBP/BCP/CsF/Al OLEDs
384(2)
Case Study
2. One-Dimensional Combinatorial Fabrication of Blue-to-Red OLEDs
386(4)
Introduction
386(1)
Experimental Procedure
387(1)
Properties of the Red-to-Blue Arrays
388(2)
Case Study
3. One-Dimensional Combinatorial Screening of Intense White OLEDs (WOLEDs)
390(4)
Introduction
390(1)
Experimental Procedure
391(1)
Properties of the WOLEDs
391(3)
Case Study
4. One-Dimensional Combinatorial Study of Forster Energy Transfer in Guest-Host OLEDs
394(6)
Introduction
394(2)
Experimental Procedure
396(1)
Forster Energy Transfer Model
397(1)
Properties of the Combinatorial Array of DCM2-Doped α-NPD/DPVBi OLEDs
397(3)
Summary and Concluding Remarks
400(5)
Acknowledgments
400(1)
References
401(4)
Combinatorial Approach to Advanced Luminescent Materials
405(20)
Jun Bao
Chen Gao
Introduction
405(1)
Combinatorial Synthesis of Phosphors: Thin Film Deposition Combined with Masks and Solution-Based Synthetic Methods
406(3)
High-Throughput Screening of Phosphors Libraries: Photography and Scanning Spectrometer System
409(3)
Combinatorial Search for Advanced Luminescent Materials
412(10)
Ultraviolet Luminescent Materials
412(2)
Vacuum Ultraviolet Luminescent Materials
414(3)
Cathodoluminescent (CL) Phosphors
417(5)
Summary and Outlook
422(3)
References
422(3)
Combinatorial Screening and Optimization of Phosphors for Flat Panel Displays and Lightings
425(22)
Kee-Sun Sohn
Namsoo Shin
Introduction
425(2)
Eu3+-Doped Y (As,NB,P,V)O4 Quaternary System
427(6)
Introduction
427(1)
Spectral and Structural Analyses of Base Compounds
427(2)
Screening Results
429(3)
The Optimum Composition
432(1)
Conclusion
433(1)
Tb3+-Doped CaO-Gd2O3-Al2O3 Ternary System
433(4)
Introduction
433(1)
Screening Results and Phase Identification
434(2)
The Optimum Composition
436(1)
Conclusions
437(1)
Genetic Algorithm-Assisted Combinatorial Chemistry (GACC)
437(10)
Introduction
437(1)
GACC and Simulations
438(4)
Experimental Results and Discussion
442(2)
Conclusions
444(1)
References
445(2)
Technology of PLD for Photodetector Materials
447(22)
Arik G. Alexanian
Nikolay S. Aramyan
Karapet E. Avjyan
Ashot M. Khachatryan
Romen P. Grigoryan
Arsham S. Yeremyan
Introduction
447(1)
Peculiarities of PLD Technology
448(2)
Synthesis of Quaternary Solid Solutions GaxIn1--xAsySb1--y (Fabrication of Semiconductor Structures with Spatial Variation of Energy Band Gap)
450(3)
Technological Approaches: Compositional and Structural Control and Description
450(1)
Approach A
451(1)
Approach B
451(2)
Fabrication of Graded Gap Semiconductor Structures
453(1)
PLD-Produced Heterojunctions (The Role of Heterojunction Interface)
453(8)
Advantages of Detectors Based on Heterostructures (An Overview)
454(1)
Technology and Structural Features
455(2)
Photodetector Characteristics and Their Relation with Heterojunction Structure
457(1)
Abrupt Heterojunction nInSb--nGaAs
457(2)
Smooth Heterojunction InSb--GaAs
459(1)
Heterojunctions pInSb-nCdTe
460(1)
Thin Films PbTe, PbSnTe, and Periodic Structures PbTe-Pba-PbTe
461(3)
Technology
462(1)
Photoelectric Characteristics
463(1)
Synthesis of Solid Solutions Bi1--xSbx
464(1)
Conclusions
465(4)
References
466(3)
Index 469


Radislav A. Potyrailo, Wilhelm F. Maier