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E-raamat: Raman Spectroscopy in Cultural Heritage Preservation

  • Formaat: EPUB+DRM
  • Sari: Cultural Heritage Science
  • Ilmumisaeg: 13-Oct-2022
  • Kirjastus: Springer International Publishing AG
  • Keel: eng
  • ISBN-13: 9783031143793
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  • Formaat: EPUB+DRM
  • Sari: Cultural Heritage Science
  • Ilmumisaeg: 13-Oct-2022
  • Kirjastus: Springer International Publishing AG
  • Keel: eng
  • ISBN-13: 9783031143793

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This book addresses the application of Raman spectroscopic techniques to a range of diverse problems which arise in the study, conservation and restoration of artefacts and sites closely related to our cultural heritage as well as in authentication. These themes are naturally wider than what at first might be considered as artworks and archaeological artefacts and the topics include pigments, paintings, ceramics, glass, sculpture and patination / corrosion, textiles, industrial archaeology, the degradation and preservation of biomaterials, mummies and human skeletal remains. An interesting feature is the inclusion of modern case studies which describe specific problems and approaches to the Raman spectral analysis of items important to our cultural heritage. The text is prefaced with an introduction to the important parameters used in nondestructive Raman measurements and also highlights some future applications based upon novel miniaturised instrumentation for in-field studies and potential screening work which will identify specimens which would repay further studies in the laboratory. An attempt is made to give a snapshot of the state-of-the-art evolution since the beginning of the technique (1970s) and to point out potential further development. The book is co-edited by three international experts with many years' experience in the application of Raman spectroscopy to artworks, archaeological artefacts and in the investigation of materials and sites for cultural heritage preservation and each editor has undertaken to write individual chapters and different topics personally. The adopted approach is designed to convey the sort of information which has become available from the adoption of analytical Raman spectroscopy to different problems in the field of cultural heritage preservation through the spectral interrogation of artefacts and how the interpretation of the spectral data can assist museum curators, archaeologists and cultural heritage historians in the preservation and conservation of ancient materials and sites : a particular advantage in this respect is the ability of Raman spectroscopy to determine –generally in a strictly noninvasive procedure - at the laboratory or on-site with mobile instruments, the presence of both organic and inorganic components in a particular specimen together nondestructively without any chemical and mechanical pretreatment being undertaken, which is an essential requirement for rare and valuable samples . An important aside from this work is the means of spectral identification of ongoing biodeterioration and biological colonisation in specimens in storage and the effects of environmental deterioration such as humidity and temperature upon their integrity.

1 Introduction
1(6)
References
5(2)
2 Historical Overview of Raman Spectroscopy
7(12)
References
14(5)
3 Theory of Raman Spectroscopy and Raman Instrumentation
19(24)
3.1 History
19(1)
3.2 The Raman Effect
20(4)
3.3 Instrumentation
24(2)
3.4 Understanding and Assignment of the Raman Spectral Signature
26(11)
3.4.1 Peak Wavenumber and Assignment
28(2)
3.4.2 Peak Intensity and Assignment
30(2)
3.4.3 Molecular and Physical Description of Vibrational Modes
32(1)
3.4.4 Implication for Spatial Resolution
32(2)
3.4.5 Symmetry and Peak Number
34(1)
3.4.6 Laser Choice and Resonance Effects
35(1)
3.4.7 Raman Tensor, Polarization: Advantages and Drawbacks
36(1)
3.4.8 Background Subtraction
36(1)
3.5 Databases: Advantages and Drawbacks
37(6)
References
38(5)
4 Combination of Raman Spectroscopy with Other Techniques (XRF, SEM-EDAXS, IR)
43(10)
4.1 Optical Microscopy and the First Raman Microscope
43(2)
4.2 Scanning and Transmission Electron Microscopy
45(1)
4.3 Castaing Microprobe (Electron Probe Micro Analyzer)
46(1)
4.4 Other Couplings
46(7)
References
48(5)
5 Pigments, Dyes and Colouring Agents
53(54)
5.1 Arts and Colours
54(2)
5.2 Raman Detection of Colouring Agents: The Advantages and Drawbacks of Raman Scattering. A Brief Historical Overview
56(4)
5.3 Colouring Agents, Dyes and Pigments: Preparation and Selection
60(1)
5.4 From Alchemy to Chemical Industry: Pigments and Dyes as Chronological/Technological Milestones
61(10)
5.5 A Few Examples Demonstrating the Advantages and Drawbacks of Raman Microspectroscopy
71(5)
5.5.1 Smalt or Lapis Lazuli?
71(2)
5.5.2 Natural or Synthetic Ultramarine
73(1)
5.5.3 High Detectivity
73(1)
5.5.4 Elimination of Wrong Conclusions Made from Elemental Analyses: Example Blue Glass/Glaze
74(1)
5.5.5 Identification of Organic Dyes (Paintings, Paper/Prints/ Inks, Textiles)
75(1)
5.6 The Interest of Non-destructive, Non-invasive and Mobile Procedures
76(1)
5.7 SERS and Associated Techniques
76(2)
5.8 Data Treatment
78(1)
5.9 Degradation and Conservation (Table 5.7)
79(1)
5.10 Dating
80(27)
References
82(25)
6 Cultural Heritage Meets the Art Forensics Enigma: Raman Spectroscopic Authentication and the Exposure of Fakes and Forgeries in Art Works
107(18)
6.1 Introduction
107(5)
6.2 Case Study 1: The Strange Case of the Disappearing Amber
112(3)
6.3 Case Study 2: The Cat with the Enigmatic Smile
115(3)
6.4 Case Study 3: When Is a Ming Porcelain Shard Not Ming Porcelain?
118(1)
6.5 Case Study 4: Analysis Baffles Expert Opinion
119(2)
6.6 Case Study 5: Is It, or Is It Not, a Genuine Specimen of an Insect Trapped in Amber?
121(1)
6.7 Summary
122(3)
References
123(2)
7 Jewellery and Gemstones
125(30)
7.1 Introduction
125(5)
7.2 Phase Identification and Characteristic Second Phases
130(3)
7.3 Provenance Studies. Multitechniques and Multivariate Analyses
133(1)
7.4 Distinguishing Gems from Glass. Fakes and Improvements
133(1)
7.5 Modern Synthetic Gems
133(1)
7.6 Case Studies
134(21)
7.6.1 Jades
134(3)
7.6.2 Corals, Pearls, Mother of Pearl
137(2)
7.6.3 Ivory and Related Compounds
139(1)
7.6.4 Ambers and Natural Resins
139(3)
7.6.5 On-Site Studies of Gems and Jewellery
142(2)
References
144(11)
8 Cave Paintings and Rock Art
155(14)
8.1 Introduction
155(3)
8.2 Rock Art and Cave Art Sites Studied by Raman Spectroscopy
158(4)
8.3 Information from Raman Spectral Data for Cultural Heritage Preservation
162(7)
References
165(4)
9 From Frescoes to Paintings
169(46)
9.1 Efficiency of Raman Microspectroscopy
169(6)
9.2 Procedures and Artefacts
175(2)
9.3 Pigments and Dyes
177(7)
9.4 Examples of Procedure: Measurements at the Laboratory and On-site
184(6)
9.5 Colour Fading and Degradation
190(3)
9.6 Conclusions
193(22)
References
193(22)
10 Analytical Raman Spectroscopy of Manuscripts and Maps: The Role of Inks
215(18)
10.1 Introduction
215(2)
10.2 The Origin and Composition of Carbon Black and Iron Gall Inks
217(1)
10.3 Iron Gall Ink and Manuscript Deterioration
218(2)
10.4 Coloured Inks
220(1)
10.5 The Detection of Ancient Inks
221(4)
10.5.1 Raman Spectroscopy
223(2)
10.6 Case Studies
225(4)
10.6.1 The Vinland Map
225(2)
10.6.2 The Beato de Valcavado Manuscript
227(1)
10.6.3 The Vercelli Gospels and the Gospel of Judas
228(1)
10.7 Conclusion
229(4)
References
229(4)
11 Patina, Corrosion and Conservation Treatments
233(18)
11.1 Mechanisms of Corrosion and Patination
233(3)
11.2 Patinas and Their Raman Signature
236(2)
11.3 Stability toward Corrosion
238(5)
11.3.1 Iron-Based Artefacts
238(3)
11.3.2 Stones and Buildings
241(1)
11.3.3 Glass
242(1)
11.4 Conservation Treatments
243(1)
11.5 Perspectives
243(8)
References
244(7)
12 Glass, Pottery and Enamelled Artefacts
251(38)
12.1 Introduction
251(2)
12.2 X04 Vibrations and the Raman Signatures of Crystalline and Glassy Silicates
253(7)
12.2.1 Structure and Raman Signature Relationship
255(5)
12.3 The Different Glass Compositions. A Brief Historical Survey
260(1)
12.4 Glass Raman Fingerprint and Resonance Raman Effect
261(8)
12.5 Glass Weathering, Dating and Conservation Treatments
269(1)
12.6 Mobile Raman Spectroscopy
270(1)
12.7 Multivariate Analysis
271(1)
12.8 Recognizing Technology Milestones - Tracing the Exchanges - Case Studies
272(17)
12.8.1 Blue (and Green) Glass Coloured with Lapis Lazuli
273(2)
12.8.2 Yellow (and Green) Colours
275(1)
12.8.3 Trade Glass Beads
276(1)
References
277(12)
13 Archaeology of Biomaterials: Mummies, Ivories, Resins and Textiles
289(42)
13.1 Introduction
289(3)
13.2 Archaeological Specimens I: Mummies and Skeletal Remains
292(19)
13.2.1 Mummified Tissue
293(10)
13.2.2 Human Skeletal Remains
303(8)
13.3 Archaeological Specimens II: Functional or Decorative Items
311(12)
13.3.1 Ivories
311(8)
13.3.2 Resins, Gums and Waxes
319(4)
13.4 Textiles
323(3)
13.4.1 The HMS Victory Sail
324(2)
13.4.2 Mummy Linens
326(1)
13.5 Conclusions
326(5)
References
326(5)
14 Raman Spectroscopy and Industrial Archaeology
331(16)
14.1 Introduction
331(2)
14.2 The Role of Analytical Chemistry
333(1)
14.3 Raman Spectroscopy and the Challenges of Industrial Archaeology
334(8)
14.3.1 Abandoned Mine of Previously Indeterminate Purpose
335(1)
14.3.2 Unexpected Hazards in Mines (St. Joachimstahl and St. Austell)
336(4)
14.3.3 Nantgarw China Works Waste Pit
340(2)
14.4 The Use of Portable Raman Spectroscopic Instrumentation
342(5)
References
345(2)
15 Raman Spectroscopic Analysis of a Putative Seventeenth Century Oil Painting Depicting William Shakespeare
347(8)
15.1 Introduction
347(3)
15.2 Experimental
350(1)
15.3 Results of the Raman Spectroscopic Analysis of the Pigments
351(1)
15.4 Interpretation of the Raman Spectral Data
351(2)
15.5 Conclusions
353(2)
References
353(2)
16 "Noli Me Tangere": A Renaissance Original? A Holistic Analytical Spectroscopic Challenge
355(16)
16.1 Introduction
355(5)
16.2 Compositional Study of the Works of Art on a Noli Me Tangere (NMT) Theme
360(3)
16.2.1 The Historical Basis of the Artworks
360(1)
16.2.2 The Nine Works of Art Comprising This Comparative Study
360(1)
16.2.3 Compositional Details Under Consideration and Comparison
361(2)
16.3 Discussion and Conclusions
363(8)
References
369(2)
17 Case Study: Raman Spectroscopic Analysis of Welsh Porcelains
371(24)
17.1 Introduction
372(2)
17.2 Experimental
374(10)
17.2.1 Specimens
374(5)
17.2.2 Spectroscopic Instrumentation
379(1)
17.2.3 Previous Analytical Work
380(4)
17.3 Results and Discussion
384(11)
17.3.1 Nantgarw and Swansea Porcelains: Statements for Verification
384(1)
17.3.2 Porcelain Body Chemistry in the Kiln
385
17.3.3 Nantgarw
200(187)
Porcelain
387(1)
17.3.4 Raman Spectroscopic Results
388(4)
References
392(3)
18 Case Study - In-field and On-site Raman Analysis
395(18)
18.1 Why On-site Analysis?
395(1)
18.2 Instrumental Requirements and On-site Procedures
396(5)
18.3 The Role of Optics
401(4)
18.4 Standoff Raman Spectroscopy
405(1)
18.5 Protection from Ambient Light
405(1)
18.6 Examples and Perspectives
406(7)
References
409(4)
19 Case Study: Non-invasively Documenting the Transfer of Enamelling Technology from Europe to China and Japan. The Role of the Jesuits in the Seventeenth Century
413(26)
19.1 The Quest for Chinese Porcelain
414(1)
19.2 The Response of European Potters
415(1)
19.3 The European and Chinese Technologies of Enamelling
416(4)
19.4 The Jesuits' Missions in Japan and China
420(1)
19.5 The Contribution of Raman Microspectroscopy
421(3)
19.6 Raman Identification of European Recipes/Ingredients in Chinese cloisonnes and Painted Enamelled Wares
424(6)
19.7 Application to Chinese Productions
430(2)
19.8 Conclusions and Perspectives
432(7)
References
432(7)
20 Case Study: The Shroud of Turin - Iconic Relic or Fake? The Role of Raman Spectroscopic Analysis in Its Forensic Appraisal
439(14)
20.1 Introduction
439(5)
20.2 The Early Scientific Evidence Relating to the Turin Shroud
444(2)
20.3 Recent Scientific Studies of the Turin Shroud Materials
446(1)
20.4 Raman Spectroscopy and the Shroud of Turin
447(6)
References
450(3)
21 Case Study: A Unique Rockingham English Porcelain Table: A Holistic Forensic Appraisal
453(10)
21.1 The Rockingham Porcelain Manufactory
453(1)
21.2 Analyses of Rockingham Porcelain
454(2)
21.3 Raman Spectroscopic Analysis of the Porcelain Table-Top
456(5)
21.3.1 Background History of Wentworth Castle
457(4)
21.4 Conclusions
461(2)
References
462(1)
22 A Little Knowledge is A Dangerous Thing: A Miscellany of Faux-Pas in the Cultural Heritage of Literature
463(16)
22.1 Preface
463(1)
22.2 Introduction
464(2)
22.3 Classical Literature in Cultural Heritage
466(13)
22.3.1 Wilkie Collins - "Armadale"
466(4)
22.3.2 Charles Dickens - A Tale of Two Cities
470(1)
22.3.3 Ross King - Ex-Libris
471(2)
22.3.4 Anthony Horowitz - The House of Silk: The New Sherlock Holmes Novel
473(2)
22.3.5 Agatha Christie-Various Novels
475(1)
References
476(3)
23 Raman Analysis: What Is Straightforward, What Is Difficult and Future Perspectives
479(6)
Selected Bibliography 485(4)
Index 489
Professor Howell G.M. Edwards M.A., B.Sc., D. Phil., C.Chem., FRSC. Howell Edwards is Professor Emeritus of Molecular Spectroscopy at the University of Bradford. He read Chemistry at Jesus College in the University of Oxford and after completing his B.A. and B.Sc. degrees he studied for his doctorate in Raman spectroscopy at Oxford with Dr Leonard Woodward and then became a

Research Fellow at Jesus College, University of Cambridge. He joined the University of Bradford as a Lecturer in Structural and Inorganic Chemistry, becoming Head of the Department of Chemical and Forensic Sciences, and was awarded a Personal Chair in Molecular Spectroscopy in 1996. He has received several international awards (Sir Harold Thompson Award; Charles Mann Award; Emanuel Boricky Medal; Norman Sheppard Award) in a spectroscopic career which has resulted in the publication of over 1350 research papers in Raman spectroscopy and the characterisation of materials, along with six books on the application of this analytical technique to art, archaeology and forensic science. He has had a lifelong interest in porcelains and the industrial archaeology , excavation and the preservation of early porcelain manufactory sites , many of which have now disappeared in urban expansion .He has authored six major books on porcelains and has also produced several monographs on the manufactories at Swansea and Nantgarw and the people associated with them. Howell Edwards is Honorary Scientific Adviser to the de Brecy Trust on the scientific evaluation of their artworks and paintings.











Professor Philippe Colomban, ENSCI engineer, M.Sc., Docteur es-Sciences Physiques. Philippe Colomban is CNRS Research Director Emeritus at Sorbonne Université. After an MSc in Ceramics, Glass & Cement Engineering (ENSCI-Sèvres) in 1975 and a MSc in Solid State Physics at Université Pierre-et-Marie Curie in 1976, Philippe Colomban obtained in 1979 the Ph.D. Hab. degree (Docteur es-Sciences Physiques) from the Université Pierre-et-Marie-Curie. He was one of the first in the world to develop Sol-Gel routes for advanced optoelectronic PLZT ceramics. He prepared single crystals, ceramics and studied their superionic conductors structure and ion and proton mobility. From 1989 to 1993 he was in charge of the new projects at the Materials Department of ONERA, the French Establishment for Aerospace Research and Development (materials for rockets and missiles, aircraft engines, Sol-Gel routes, ceramic- or polymer-matrix composites, fibres, nanoparticle-based microwave absorbing materials and Functionally Graded composites) and worked as Consultant at the ONERA for 10 further years. From 1994 to the present, as CNRS Research Professor his research interests include Materials Science and Raman, IR and neutron spectroscopy (in situ analysis, fuel cells, electrolysis, fibres/composites). Attention is paid to the correlation between Raman parameters and mechanical and electrical (ionic, electronic) propertiesas well to the identification of the technology used in ancient ceramics, glasses, paintings and buildings. Ph. Colomban has published two books, more than 500 peer-reviewed papers, many book chapters and has applied for 10 patents; he has presented more than 100 invited talks and was visiting professor in Japan, Korea, South Africa, and Tunisia. He is Associated Editor of the Journal of Raman Spectroscopy and member of several Editorial Boards of journals devoted to Spectroscopy, Materials Science or Archaeometry.











Professor Peter Vandenabeele, is a professor at Ghent University and head of the Raman spectroscopy research group. He is a doctor in analytical chemistry and has performed research on applications of Raman spectroscopy in several research fields, including cultural heritage artefacts. He is member of the department of Archaeology at Ghent University and an associated member of the department of Chemistry at the same institution. His main research topics involve novel applications of Raman spectroscopy, especially involving the development and application of mobile instrumentation. Until the present time, Peter Vandenabeele has co-authored 170+ research papers and several books on this research topic and often gives invited presentations at international conferences.