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E-raamat: Solid State Materials Chemistry

(University of Durham), (University of South Carolina), (Ohio State University), (Universitetet i Oslo)
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  • Ilmumisaeg: 01-Apr-2021
  • Kirjastus: Cambridge University Press
  • Keel: eng
  • ISBN-13: 9781009028479
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  • Formaat: PDF+DRM
  • Ilmumisaeg: 01-Apr-2021
  • Kirjastus: Cambridge University Press
  • Keel: eng
  • ISBN-13: 9781009028479

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This comprehensive textbook provides a modern, self-contained treatment for upper undergraduate and graduate level students. It emphasizes the links between structure, defects, bonding, and properties throughout, and provides an integrated treatment of a wide range of materials, including crystalline, amorphous, organic and nano- materials. Boxes on synthesis methods, characterization tools, and technological applications distil specific examples and support student understanding of materials and their design. The first six chapters cover the fundamentals of extended solids, while later chapters explore a specific property or class of material, building a coherent framework for students to master core concepts with confidence, and for instructors to easily tailor the coverage to fit their own single semester course. With mathematical details given only where they strengthen understanding, 400 original figures and over 330 problems for hands-on learning, this accessible textbook is ideal for courses in chemistry and materials science.

A modern treatment of the field for upper-level undergraduate and graduate courses in chemistry and materials science. chemistry. With over 330 problems and 400 original figures, this thorough text covers a range of materials in an accessible and integrated manner, including inorganic and organic, crystalline and amorphous, bulk and nano- materials.

Arvustused

'This book will be invaluable to students, educators, and researchers studying inorganic materials chemistry. The breadth is impressive, with the fundamentals of the subject covered well, and followed by chapters that highlight optical, electronic, magnetic, porous, energy, and other applications of functional materials. Graduate-level problems on each topic support the educational aspects, and up-to-date case studies throughout make this an extremely useful resource for professional materials researchers.' Paul Attfield, University of Edinburgh 'Finally, we have a substantial textbook that addresses a gap in our teaching tools when it comes to solid state chemistry. This detailed work covers many fundamental aspects of solid state and materials chemistry at a level appropriate for students. A textbook of this type has been sought by advanced undergraduates, graduate students, and faculty for some time, and will serve well in classes teaching this subject.' Mercouri G. Kanatzidis, Northwestern University 'A readable, rigorous, and modern account of the fundamentals of solid state chemistry and materials' properties. This will be valuable for undergraduate and graduate programs in chemistry. Questions commonly posed by students are well anticipated and the concepts are discussed with thoughtful clarity. I will certainly recommend it to my students.' Simon J. Clarke, University of Oxford 'This comprehensive textbook will become the essential standard for any course in solid state / materials chemistry from advanced undergraduate to beginning graduate levels. Space group symmetry, phase diagrams, electronic structure and properties of solids, defects and non-stoichiometry, and much more - it's all here in one volume instead of the myriad sources which I (and many others) used over the past 30+ years to cobble together a coherent course.' John Greedan, McMaster University 'This contemporary treatment of functional materials efficiently covers the fundamentals of solid state materials chemistry. Property-specific chapters inform readers of both the broader applications and pertinent scientific concepts of the most important classes of solid materials. The concise writing style, consistent incorporation of figures, and thoughtful variety of problems make this approachable textbook well suited for advanced undergraduate and graduate students.' Michael Lufaso, University of North Florida 'Solid State Materials Chemistry, at almost 700 pages, is both a textbook and an essential reference, intended primarily for advanced students of chemistry for use in upper-level graduate courses. The authors cover the entirety of modern inorganic structural chemistry and solid state chemistry. They have merged these two fields into a single comprehensive resource as Solid State Materials Chemistry.' Kenneth Poeppelmeier, Northwestern University 'A fascinating, authoritative, and truly modern book that fulfills a long-felt need; the kind of book that one acquires as an undergraduate and then uses as a text and reference for the rest of one's active career.' Ram Seshadri, University of California, Santa Barbara 'This excellent book provides a complete resource for both undergraduate and graduate students interested in the fascinating world of functional materials, and promises to become the go-to text for solid state chemistry courses. Each chapter contains numerous examples that demonstrate how the properties relate to the structure of the material, carefully linking theory with practice. The self-contained chapters allow readers to map their own journey.' Brendan Kennedy, University of Sydney 'A very welcome book written by four of the most renowned solid-state chemists of our time, with undergraduate and graduate chemistry students in mind. This makes the book a unique resource to enter into the complex and fascinating chemistry and physics of matter in the solid state without having to deal with the most complex physical and mathematical details. I will for sure use this book in my Materials Chemistry course and I am sure it would be of use to lecturers worldwide' Leopoldo Suescun, Acta Crystallographica Section B 'The book offers a comprehensive and insightful exploration of the subject matter, with well-researched and thoughtfully presented topics. The clear structure and appealing design facilitate an engaging reading experience. The format is user-friendly, making the content accessible for students.' Fabian Martinez, University of California, San Diego

Muu info

A modern and thorough treatment of the field for upper-level undergraduate and graduate courses in materials science and chemistry.
Preface xvii
Acknowledgments xix
1 Structures of Crystalline Materials
1(53)
1.1 Symmetry
1(12)
1.1.1 Translational Symmetry
2(1)
1.1.2 Rotational Symmetry
3(2)
1.1.3 Crystallographic Point Groups and Crystal Systems
5(1)
1.1.4 Bravais Lattices
5(3)
1.1.5 Introduction to Space Groups
8(1)
1.1.6 Symmetry Elements That Combine Rotation and Translation
9(2)
1.1.7 Space-Group Symbols
11(1)
1.1.8 Description of a Crystal Structure
12(1)
1.2 Databases
13(1)
1.3 Composition
14(4)
1.3.1 Coordination, Stoichiometry, and Connectivity
15(2)
1.3.2 The Generalized 8--N Rule
17(1)
1.4 Structural Principles
18(20)
1.4.1 Packing of Spheres
19(3)
1.4.2 Filling Holes
22(6)
1.4.3 Network Structures
28(4)
1.4.4 Polyhedral Structures
32(6)
1.5 Structures of Selected Materials
38(10)
1.5.1 The Spinel Structure
38(1)
1.5.2 The Garnet Structure
39(1)
1.5.3 Perovskite Structures
40(4)
1.5.4 Silicates
44(2)
1.5.5 Zeolites
46(1)
1.5.6 Zintl Phases
47(1)
1.6 Problems
48(3)
1.7 Further Reading
51(1)
1.8 References
51(3)
2 Defects and More Complex Structures
54(33)
2.1 Point Defects in Crystalline Elemental Solids
54(1)
2.2 Intrinsic Point Defects in Compounds
55(3)
2.3 Thermodynamics of Vacancy Formation
58(3)
2.4 Extrinsic Defects
61(2)
2.5 Solid Solutions and Vegard's Law
63(2)
2.6 Kroger--Vink Notation
65(1)
2.7 Line Defects in Metals
66(1)
2.7.1 Edge Dislocations
66(1)
2.7.2 Screw Dislocations
66(1)
2.8 Planar Defects in Materials
67(8)
2.8.1 Stacking Faults
67(1)
2.8.2 Twinning
68(4)
2.8.3 Antiphase Boundaries
72(2)
2.8.4 Crystallographic Shear Structures
74(1)
2.9 Gross Nonstoichiometry and Defect Ordering
75(3)
2.10 Incommensurate Structures
78(2)
2.11 Infinitely Adaptive Structures
80(1)
2.12 Problems
81(4)
2.13 Further Reading
85(1)
2.14 References
85(2)
3 Defect Chemistry and Nonstoichiometry
87(33)
3.1 Narrow Nonstoichiometry in Oxides
87(11)
3.1.1 Point Defects in a Pure Stoichiometric Oxide
87(1)
3.1.2 Point Defects upon Oxidation/Reduction of the Stoichiometric Oxide
88(1)
3.1.3 Equilibrium Equations for Oxidative and Reductive Nonstoichiometry
89(1)
3.1.4 Defect Equilibria for Schottky-Type Redox Compensation
90(3)
3.1.5 Acceptor-Doped Oxides
93(1)
3.1.6 Donor-Doped Oxides
94(1)
3.1.7 Solid Solubility of Dopants
94(2)
3.1.8 Cautionary Note on Defect Models in Pure Oxides
96(2)
3.2 Wide Nonstoichiometry in Oxides
98(1)
3.3 Point Defects and Diffusion
99(16)
3.3.1 Point-Defect Movements
101(2)
3.3.2 Random Hopping
103(1)
3.3.3 Hopping Under a Driving Force
104(1)
3.3.4 Hopping Under a Concentration Gradient
105(1)
3.3.5 Hopping Under an Electric Field
106(1)
3.3.6 Relationship between Conductivity and Diffusivity
107(1)
3.3.7 Ambipolar Diffusion
108(3)
3.3.8 Temperature Dependence of Diffusivity
111(1)
3.3.9 Diffusivity and Redox Defect Equilibria
111(1)
3.3.10 Outline of Non-Steady-State Diffusion
112(2)
3.3.11 Cautionary Note on Diffusion in Real Materials
114(1)
3.4 Problems
115(3)
3.5 Further Reading
118(1)
3.6 References
118(2)
4 Phase Diagrams and Phase Transitions
120(34)
4.1 Phase Diagrams
120(3)
4.2 Two-Component Phase Diagrams
123(8)
4.2.1 Without Compound Formation
123(2)
4.2.2 With Compound Formation
125(3)
4.2.3 Solid-Solution Formation
128(3)
4.3 Three-Component Phase Diagrams
131(4)
4.4 Structural Phase Transitions
135(15)
4.4.1 Classification of Phase Transitions
136(1)
4.4.2 Symmetry and Order Parameters
137(3)
4.4.3 Introduction to Landau Theory
140(1)
4.4.4 Second-Order Transitions
141(3)
4.4.5 First-Order and Tricritical Transitions
144(3)
4.4.6 Phonons, Soft Modes, and Displacive Transitions
147(3)
4.5 Problems
150(2)
4.6 Further Reading
152(1)
4.7 References
153(1)
5 Chemical Bonding
154(46)
5.1 Ionic Bonding
154(7)
5.1.1 Coulombic Potential Energy
154(2)
5.1.2 Lattice Energy and the Born--Mayer Equation
156(2)
5.1.3 Experimental versus Calculated Lattice-Formation Energies
158(3)
5.2 Atomic Orbitals
161(8)
5.2.1 Energies of Atomic Orbitals
166(2)
5.2.2 Sizes of Atomic Orbitals
168(1)
5.3 Molecular-Orbital Theory
169(21)
5.3.1 Homonuclear Diatomics: H2+ and H2
169(4)
5.3.2 The Heteronuclear Diatomic Case: HHe
173(1)
5.3.3 Orbital Overlap and Symmetry
174(1)
5.3.4 Combination of σ and π Bonding: O2
175(2)
5.3.5 Symmetry-Adapted Linear Combinations (SALCs)
177(2)
5.3.6 Simple Polyatomic Molecules: BeH2 and CH4
179(2)
5.3.7 Conjugated π Bonding: C6H6
181(2)
5.3.8 Transition-Metal Complexes: [ CrCl6]3- and [ CoCl4]2-
183(3)
5.3.9 High-and Low-Spin Configurations
186(2)
5.3.10 Jahn--Teller Distortions
188(2)
5.4 Bond Valences
190(5)
5.5 Problems
195(3)
5.6 Further Reading
198(1)
5.7 References
199(1)
6 Electronic Band Structure
200(43)
6.1 The Band Structure of a Hydrogen-Atom Chain
200(10)
6.1.1 The Electronic Structures of Cyclic HN Molecules
201(1)
6.1.2 Translational Symmetry and the Bloch Function
202(1)
6.1.3 The Quantum Number k
203(1)
6.1.4 Visualizing Crystal Orbitals
204(3)
6.1.5 Band-Structure Diagrams
207(2)
6.1.6 Density-of-States (DOS) Plots
209(1)
6.2 The Band Structure of a Chain of H2 Molecules
210(3)
6.3 Electrical and Optical Properties
213(2)
6.3.1 Metals, Semiconductors, and Insulators
213(1)
6.3.2 Direct- versus Indirect-Gap Semiconductors
214(1)
6.4 Representing Band Structures in Higher Dimensions
215(5)
6.4.1 Crystal Orbitals in Two Dimensions
215(4)
6.4.2 Crystal Orbitals in Three Dimensions
219(1)
6.5 Band Structures of Two-Dimensional Materials
220(7)
6.5.1 Graphene
221(2)
6.5.2 CuO22- Square Lattice
223(4)
6.6 Band Structures of Three-Dimensional Materials
227(10)
6.6.1 α-Polonium
227(1)
6.6.2 Diamond
228(2)
6.6.3 Elemental Semiconductors
230(1)
6.6.4 Rhenium Trioxide
231(2)
6.6.5 Perovskites
233(4)
6.7 Problems
237(4)
6.8 Further Reading
241(1)
6.9 References
242(1)
7 Optical Materials
243(58)
7.1 Light, Color, and Electronic Excitations
243(2)
7.2 Pigments, Dyes, and Gemstones
245(1)
7.3 Transitions between d Orbitals (d-to-d Excitations)
246(12)
7.3.1 Ligand-and Crystal-Field Theory
246(2)
7.3.2 Absorption Spectra and Spectroscopic Terms
248(4)
7.3.3 Correlation Diagrams
252(3)
7.3.4 Selection Rules and Absorption Intensity
255(3)
7.4 Charge-Transfer Excitations
258(3)
7.4.1 Ligand-to-Metal Charge Transfer
259(1)
7.4.2 Metal-to-Metal Charge Transfer
260(1)
7.5 Compound Semiconductors
261(4)
7.5.1 Optical Absorbance, Band Gap, and Color
262(1)
7.5.2 Electronegativity, Orbital Overlap, and Band Gap
263(2)
7.6 Conjugated Organic Molecules
265(2)
7.7 Luminescence
267(1)
7.8 Photoluminescence
268(19)
7.8.1 Components of a Phosphor
268(2)
7.8.2 Radiative Return to the Ground State
270(2)
7.8.3 Thermal Quenching
272(2)
7.8.4 Lanthanoid Activators
274(5)
7.8.5 Non-Lanthanoid Activators
279(2)
7.8.6 Energy Transfer
281(2)
7.8.7 Sensitizers
283(1)
7.8.8 Concentration Quenching and Cross Relaxation
284(1)
7.8.9 Up-Conversion Photoluminescence
285(2)
7.9 Electroluminescence
287(4)
7.9.1 Inorganic Light-Emitting Diodes (LEDs)
287(2)
7.9.2 Organic Light-Emitting Diodes (OLEDs)
289(2)
7.10 Materials for Lighting
291(3)
7.10.1 Fluorescent Lamp Phosphors
292(1)
7.10.2 Phosphor-Converted LEDs for White Light
293(1)
7.11 Problems
294(4)
7.12 Further Reading
298(1)
7.13 References
299(2)
8 Dielectrics and Nonlinear Optical Materials
301(48)
8.1 Dielectric Properties
301(8)
8.1.1 Dielectric Permittivity and Susceptibility
302(1)
8.1.2 Polarization and the Clausius--Mossotti Equation
303(2)
8.1.3 Microscopic Mechanisms of Polarizability
305(1)
8.1.4 Frequency Dependence of the Dielectric Response
306(2)
8.1.5 Dielectric Loss
308(1)
8.2 Dielectric Polarizabilities and the Additivity Rule
309(4)
8.3 Crystallographic Symmetry and Dielectric Properties
313(1)
8.4 Pyroelectricity and Ferroelectricity
314(7)
8.4.1 Ferroelectricity in BaTiO3
314(5)
8.4.2 Antiferroelectricity
319(2)
8.5 Piezoelectricity
321(3)
8.6 Local Bonding Considerations in Non-Centrosymmetric Materials
324(6)
8.6.1 Second-Order Jahn--Teller Distortions with d0 Cations
325(2)
8.6.2 Second-Order Jahn--Teller Distortions with s2p0 Cations
327(3)
8.7 Nonlinear Optical Materials
330(1)
8.8 Nonlinear Susceptibility and Phase Matching
331(3)
8.9 Important SHG Materials
334(9)
8.9.1 KH2PO4
336(1)
8.9.2 KTiOPO4
336(2)
8.9.3 Niobates and Tantalates
338(1)
8.9.4 Organic and Polymer NLO Materials
339(1)
8.9.5 Borates
340(3)
8.10 Problems
343(3)
8.11 Further Reading
346(1)
8.12 References
346(3)
9 Magnetic Materials
349(47)
9.1 Magnetic Materials and Their Applications
349(1)
9.2 Physics of Magnetism
349(7)
9.2.1 Bar Magnets and Atomic Magnets
349(3)
9.2.2 Magnetic Intensity, Induction, Energy, Susceptibility, and Permeability
352(3)
9.2.3 Unit Systems in Magnetism
355(1)
9.3 Types of Magnetic Materials
356(1)
9.4 Atomic Origins of Magnetism
357(10)
9.4.1 Electron Movements Contributing to Magnetism and Their Quantization
357(2)
9.4.2 Atomic Magnetic Moments
359(4)
9.4.3 Magnetic Moments for 3d Ions in Compounds
363(3)
9.4.4 Magnetic Moments for Af Ions in Compounds
366(1)
9.4.5 Note on Magnetic Moments of Ad and 5d Metals in Compounds
366(1)
9.5 Diamagnetism
367(1)
9.6 Paramagnetism
367(5)
9.6.1 Curie and Curie--Weiss Paramagnetism
368(3)
9.6.2 Pauli Paramagnetism
371(1)
9.7 Antiferromagnetism
372(2)
9.8 Superexchange Interactions
374(3)
9.9 Ferromagnetism
377(8)
9.9.1 Ferromagnetic Insulators and Half-Metals
381(1)
9.9.2 Ferromagnetic Metals
382(2)
9.9.3 Superferromagnets
384(1)
9.10 Ferrimagnetism
385(2)
9.11 Frustrated Systems and Spin Glasses
387(1)
9.12 Magnetoelectric Multiferroics
388(1)
9.13 Molecular and Organic Magnets
389(2)
9.14 Problems
391(3)
9.15 Further Reading
394(1)
9.16 References
394(2)
10 Conducting Materials
396(61)
10.1 Conducting Materials
396(2)
10.2 Metals
398(16)
10.2.1 Drude Model
398(4)
10.2.2 Free-Electron Model
402(1)
10.2.3 Fermi--Dirac Distribution
403(2)
10.2.4 Carrier Concentration
405(1)
10.2.5 Carrier Mobility and Effective Mass
406(1)
10.2.6 Fermi Velocity
407(2)
10.2.7 Scattering Mechanisms
409(2)
10.2.8 Band Structure and Conductivity of Aluminum
411(1)
10.2.9 Band Structures and Conductivity of Transition Metals
412(2)
10.3 Semiconductors
414(14)
10.3.1 Carrier Concentrations in Intrinsic Semiconductors
414(2)
10.3.2 Doping
416(3)
10.3.3 Carrier Concentrations and Fermi Energies in Doped Semiconductors
419(2)
10.3.4 Conductivity
421(1)
10.3.5 p--n Junctions
422(3)
10.3.6 Light-Emitting Diodes and Photovoltaic Cells
425(1)
10.3.7 Transistors
426(2)
10.4 Transition-Metal Compounds
428(9)
10.4.1 Electron Repulsion: The Hubbard Model
428(3)
10.4.2 Transition-Metal Compounds with the NaCl-Type Structure
431(3)
10.4.3 Transition-Metal Compounds with the Perovskite Structure
434(3)
10.5 Organic Conductors
437(8)
10.5.1 Conducting Polymers
438(3)
10.5.2 Polycyclic Aromatic Hydrocarbons
441(2)
10.5.3 Charge-Transfer Salts
443(2)
10.6 Carbon
445(6)
10.6.1 Graphene
445(2)
10.6.2 Carbon Nanotubes
447(4)
10.7 Problems
451(3)
10.8 Further Reading
454(1)
10.9 References
455(2)
11 Magnetotransport Materials
457(29)
11.1 Magnetotransport and Its Applications
457(1)
11.2 Charge, Orbital, and Spin Ordering in Iron Oxides
458(7)
11.2.1 The Verwey Transition in Magnetite, Fe3O4
458(2)
11.2.2 Double-Cell Perovskite, YBaFe2O5
460(2)
11.2.3 CaFeO3 and SrFeO3
462(3)
11.3 Charge and Orbital Ordering in Perovskite-Type Manganites
465(7)
11.3.1 Spin and Orbital Ordering in CaMnO3 and LaMnO3
465(3)
11.3.2 The La1-xCaxMnO3 Phase Diagram
468(2)
11.3.3 Tuning the Colossal Magnetoresistance
470(2)
11.4 Half-Metals and Spin-Polarized Transport
472(9)
11.4.1 Magnetoresistant Properties of Half-Metals
472(4)
11.4.2 CrO2
476(1)
11.4.3 Heusler Alloys
477(3)
11.4.4 Half-Metals with Valence-Mixing Itinerant Electrons
480(1)
11.5 Problems
481(2)
11.6 Further Reading
483(1)
11.7 References
483(3)
12 Superconductivity
486(43)
12.1 Overview of Superconductivity
486(2)
12.2 Properties of Superconductors
488(4)
12.3 Origins of Superconductivity and BCS Theory
492(8)
12.4 C60-Derived Superconductors
500(5)
12.5 Molecular Superconductors
505(4)
12.6 BaBiO3 Perovskite Superconductors
509(2)
12.7 Cuprate Superconductors
511(10)
12.7.1 La2CuO4 "214" Materials
512(1)
12.7.2 YBa2Cu3O7-δ "YBCO" or "123" Materials
513(3)
12.7.3 Other Cuprates
516(1)
12.7.4 Electronic Properties of Cuprates
517(4)
12.8 Iron Pnictides and Related Superconductors
521(2)
12.9 Problems
523(3)
12.10 Further Reading
526(1)
12.11 References
526(3)
13 Energy Materials: Ionic Conductors, Mixed Conductors, and Intercalation Chemistry
529(50)
13.1 Electrochemical Cells and Batteries
529(3)
13.2 Fuel Cells
532(1)
13.3 Conductivity in Ionic Compounds
533(3)
13.4 Superionic Conductors
536(4)
13.4.1 AgI: A Cation Superionic Conductor
536(3)
13.4.2 PbF2: An Anionic Superionic Conductor
539(1)
13.5 Cation Conductors
540(5)
13.5.1 Sodium β-alumina
540(2)
13.5.2 Other Ceramic Cation Conductors
542(1)
13.5.3 Polymeric Cation Conductors
543(2)
13.6 Proton Conductors
545(4)
13.6.1 Water-Containing Proton Conductors
546(1)
13.6.2 Acid Salts
547(1)
13.6.3 Perovskite Proton Conductors
548(1)
13.7 Oxide-Ion Conductors
549(6)
13.7.1 Fluorite-Type Oxide-Ion Conductors
552(1)
13.7.2 Perovskite, Aurivillius, Brownmillerite, and Other Oxide Conductors
553(2)
13.7.3 SOFC Electrode Materials and Mixed Conductors
555(1)
13.8 Intercalation Chemistry and Its Applications
555(18)
13.8.1 Graphite Intercalation Chemistry
556(3)
13.8.2 Lithium Intercalation Chemistry and Battery Electrodes
559(2)
13.8.3 Lithium-Ion Batteries with Oxide Cathodes
561(7)
13.8.4 Electrochemical Characteristics of Lithium Batteries
568(1)
13.8.5 Other Lithium Battery Electrode Materials
569(4)
13.9 Problems
573(3)
13.10 Further Reading
576(1)
13.11 References
576(3)
14 Zeolites and Other Porous Materials
579(40)
14.1 Zeolites
579(18)
14.1.1 Representative Structures of Zeolites
581(5)
14.1.2 Roles of Template Molecules in Zeolite Synthesis
586(2)
14.1.3 Zeolites in Catalysis
588(5)
14.1.4 Ion-Exchange Properties
593(2)
14.1.5 Drying Agents, Molecular Sieving, and Sorption
595(1)
14.1.6 AlPOs and Related Materials
596(1)
14.2 Mesoporous Aluminosilicates
597(3)
14.3 Other Porous Oxide Materials
600(5)
14.4 Metal--Organic Frameworks (MOFs)
605(7)
14.4.1 MOF Structures
605(3)
14.4.2 Some Applications of MOFs
608(4)
14.5 Problems
612(3)
14.6 Further Reading
615(1)
14.7 References
616(3)
15 Amorphous and Disordered Materials
619(36)
15.1 The Atomic Structure of Glasses
620(2)
15.2 Topology and the Structure of Glasses
622(3)
15.3 Oxide Glasses
625(1)
15.4 Optical Properties and Refractive Index
625(6)
15.5 Optical Fibers
631(2)
15.6 Nucleation and Growth
633(1)
15.7 The Glass Transition
634(5)
15.8 Strong and Fragile Behavior of Liquids and Melts
639(3)
15.9 Low-Temperature Dynamics of Amorphous Materials
642(2)
15.10 Electronic Properties: Anderson Localization
644(3)
15.11 Metallic Glasses
647(4)
15.12 Problems
651(1)
15.13 Further Reading
652(1)
15.14 References
652(3)
Appendix A Crystallographic Point Groups in Schonflies Symbolism 655(1)
Appendix B International Tables for Crystallography 656(5)
Appendix C Nomenclature of Silicates 661(1)
Appendix D Bond-Valence Parameters in Solids 662(1)
Appendix E The Effect of a Magnetic Field on a Moving Charge 663(1)
Appendix F Coupling j--j 664(1)
Appendix G The Langevin Function 665(1)
Appendix H The Brillouin Function 666(4)
Appendix I Measuring and Analyzing Magnetic Properties 670(2)
Appendix J Fundamental Constants of Exact Value 672(1)
References for Appendices 673(1)
Index 674
Patrick M. Woodward is a Professor in the Department of Chemistry and Biochemistry at Ohio State University. His research interests include materials discovery and the study of structure-property relationships in extended solids. He has served as chair of the Solid State Chemistry Gordon Conference (2018) and as Associate Editor of the Journal of Solid State Chemistry (20062011). Pavel Karen is a Professor in the Department of Chemistry at the University of Oslo, where he teaches inorganic and solid-state chemistry with a focus on crystallography. He works experimentally with mixed-valence compounds, and studies their crystal structures by X-ray and neutron diffraction, local structures by Mössbauer spectroscopy (collaboration) and phase transitions by calorimetry. John S. O. Evans is a Professor in the Department of Chemistry at Durham University, where he served as Head of Department from 2009 to 2014. His research interests are in structural materials chemistry and powder diffraction methods. His awards include the 1997 RSC Meldola medal and the 2015 RSC Teamwork in Innovation co-award for collaborative research with industry. Thomas Vogt is a Professor and Educational Foundation Endowed Chair in the Department of Chemistry and Biochemistry, Director of the NanoCenter, and adjunct Professor of Philosophy at the University of South Carolina. He is a Fellow of the American Physical Society, the American Association for the Advancement of Science and the Neutron Scattering Society of America.