- Presents a solid introduction to thermal analysis, methods, instrumentation, calibration, and application along with the necessary theoretical background.
- Useful to chemists, physicists, materials scientists, and engineers who are new to thermal analysis techniques, and to existing users of thermal analysis who wish expand their experience to new techniques and applications
- Topics covered include Differential Scanning Calorimetry and Differential Thermal Analysis (DSC/DTA), Thermogravimetry, Thermomechanical Analysis and Dilatometry, Dynamic Mechanical Analysis, Micro-Thermal Analysis, Hot Stage Microscopy, and Instrumentation.
- Written by experts in the various areas of thermal analysis
- Relevant and detailed experiments and examples follow each chapter.
Arvustused
"I have read it with great pleasure and it is my honor to provide this short review. Let me congratulate the editors on the concept of this book. They managed to tune the balance between basic principles and practical information finely . . .In conclusion I think that this book is very useful for students, PhDs, and researchers who are dealing or intended to deal with thermal analysis of polymers." (J Therm Anal Calorim, 2010)
| Preface |
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ix | |
| Introduction |
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1 | (6) |
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Differential Scanning Calorimetry (DSC) |
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7 | (234) |
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7 | (2) |
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Elements of Thermodynamics in DSC |
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9 | (9) |
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The Basics of Differential Scanning Calorimetry |
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18 | (19) |
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Purity Determination of Low-Molecular-Mass Compounds by DSC |
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37 | (4) |
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Calibration of Differential Scanning Calorimeters |
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41 | (11) |
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Measurement of Heat Capacity |
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52 | (6) |
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Phase Transitions in Amorphous and Crystalline Polymers |
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58 | (57) |
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115 | (8) |
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123 | (7) |
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130 | (24) |
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Differential Photocalorimetry (DPC) |
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154 | (8) |
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162 | (6) |
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Modulated Temperature Differential Scanning Calorimetry (MTDSC) |
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168 | (40) |
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How to Perform DSC Measurements |
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208 | (9) |
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217 | (24) |
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225 | (1) |
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225 | (4) |
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229 | (12) |
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Thermogravimetric Analysis (TGA) |
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241 | (78) |
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241 | (1) |
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Background Principles and Measurement Modes |
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242 | (9) |
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Calibration and Reference Materials |
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251 | (5) |
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Measurements and Analyses |
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256 | (21) |
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277 | (18) |
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295 | (13) |
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308 | (11) |
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311 | (1) |
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312 | (2) |
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314 | (5) |
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Thermomechanical Analysis (TMA) and Thermodilatometry (TD) |
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319 | (68) |
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319 | (1) |
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320 | (6) |
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326 | (6) |
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332 | (3) |
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How to Perform a TMA Experiment |
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335 | (5) |
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340 | (23) |
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Selected Industrial Applications (with Details of Experimental Conditions) |
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363 | (24) |
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378 | (2) |
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380 | (1) |
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381 | (6) |
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Dynamic Mechanical Analysis (DMA) |
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387 | (110) |
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387 | (7) |
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Characterization of Viscoelastic Behavior |
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394 | (7) |
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The Relationship between Time, Temperature, and Frequency |
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401 | (9) |
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Applications of Dynamic Mechanical Analysis |
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410 | (14) |
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Examples of DMA Characterization for Thermoplastics |
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424 | (8) |
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Characteristics of Fibers and Thin Films |
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432 | (6) |
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DMA Characterization Crosslinked Polymers |
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438 | (18) |
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Practical Aspects of Conducting DMA Experiments |
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456 | (21) |
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Commericial DMA Instrumentation |
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477 | (20) |
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488 | (1) |
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489 | (2) |
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491 | (6) |
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Dielectric Analysis (DEA) |
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497 | (118) |
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497 | (5) |
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Theory and Background of Dielectric Analysis |
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502 | (18) |
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520 | (8) |
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Performing Dielectric Experiments |
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528 | (10) |
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Typical Measurements on Poly(Methyl Methacrylate) (PMMA) |
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538 | (15) |
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Dielectric Analysis of Thermoplastics |
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553 | (23) |
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Dielectric Analysis of Thermosets |
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576 | (16) |
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592 | (23) |
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599 | (1) |
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599 | (4) |
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603 | (12) |
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Micro- and Nanocale Local Thermal Analysis |
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615 | (36) |
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615 | (1) |
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The Atomic Force Microscope |
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616 | (2) |
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Scanning Thermal Microscopy |
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618 | (2) |
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Thermal Probe Design and Spatial Resolution |
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620 | (4) |
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Measuring Thermal Conductivity and Thermal Force-Distance Curves |
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624 | (4) |
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628 | (5) |
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Performing a Micro/Nanoscale Thermal Analysis Experiment |
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633 | (4) |
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Examples of Micro/Nanoscale Thermal Analysis Applications |
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637 | (7) |
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Overview of Local Thermal Analysis |
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644 | (7) |
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647 | (1) |
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648 | (3) |
| Index |
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651 | |
Joseph D. Menczel, PhD, a recognized expert in thermal analysis of polymers with some thirty years of industrial and academic experience, is Assistant Technical Director at Alcon Laboratories. He has researched more than 120 polymeric systems in which he studied calibration of DSCs, glass transition, nucleation, crystallization, melting, stability, mechanical and micro-mechanical properties of polymers, and polymer-water interactions. Dr. Menczel holds six patents and is the author of seventy scholarly papers. He is the author of two chapters in the bookThermal Characterization of Polymeric Materials. In conducting DSC experiments, Dr. Menczel found a crystal/amorphous interface in semicrystalline polymers, which later became known as the rigid amorphous phase. He is also credited with developing the temperature calibration of DSCs for cooling experiments.
R. Bruce Prime, PhD, is a consultant to industry and government and a recognized authority on the cure and properties of cross-linked polymer systems. During his thirty-year career with IBM, he led teams responsible for developing and implementing polymer applications for printer and information storage technologies. He holds four patents and is the author of more than fifty technical papers and the chapter on thermosets in Thermal Characterization of Polymeric Materials. Dr. Prime is a Fellow of SPE and NATAS and was the 1989 recipient of the Mettler-Toledo Award in Thermal Analysis. He maintains the Web site www.primethermosets.com.
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