Klienditugi: 7440010 (E-R 10-18)

E-raamat: Epitaxial Growth of Complex Metal Oxides

Edited by Guus Rijnders (Professor, MESA+ Institute for Nanotec), Edited by Mark Huijben (Professor, MESA+ Institute for Nanotechnology, University of Twente, Enschede, The Netherlands.), Edited by Gertjan Koster (Professor, MESA+ Institute for Nanotechnology,University of Twente, Enschede, The Netherlands)

Formaat: PDF+DRM
Sari: Woodhead Publishing Series in Electronic and Optical Materials
Ilmumisaeg: 22-Apr-2022
Kirjastus: Woodhead Publishing Ltd
Keel: eng
ISBN-13: 9780081029466

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Formaat: PDF+DRM
Sari: Woodhead Publishing Series in Electronic and Optical Materials
Ilmumisaeg: 22-Apr-2022
Kirjastus: Woodhead Publishing Ltd
Keel: eng
ISBN-13: 9780081029466

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Epitaxial Growth of Complex Metal Oxides, Second Edition reviews techniques and recent developments in the fabrication quality of complex metal oxides, which are facilitating advances in electronic, magnetic and optical applications. Sections review the key techniques involved in the epitaxial growth of complex metal oxides and explore the effects of strain and stoichiometry on crystal structure and related properties in thin film oxides. Finally, the book concludes by discussing selected examples of important applications of complex metal oxide thin films, including optoelectronics, batteries, spintronics and neuromorphic applications.

This new edition has been fully updated, with brand new chapters on topics such as atomic layer deposition, interfaces, STEM-EELs, and the epitaxial growth of multiferroics, ferroelectrics and nanocomposites.

Examines the techniques used in epitaxial thin film growth for complex oxides, including atomic layer deposition, sputtering techniques, molecular beam epitaxy, and chemical solution deposition techniques
Reviews materials design strategies and materials property analysis methods, including the impacts of defects, strain, interfaces and stoichiometry
Describes key applications of epitaxially grown metal oxides, including optoelectronics, batteries, spintronics and neuromorphic applications

List of contributors

Preface

Part One

(156)

1 Growth studies of heteroepitaxial oxide thin films using reflection high-energy electron diffraction

(34)

Gertjan Koster

Yorick Birkhblzer

Mark Huijben

Guus Rijnders

Matjaz Spreitzer

Lior Kornblum

Sander Smink

1 Introduction: RHEED and pulsed laser deposition

(1)

2 Basic principles of RHEED

(1)

3 Variations of the specular intensity during deposition

(2)

4 RHEED intensity variations during heteroepitaxy: examples

(12)

5 Other templates

(9)

6 Postdeposition RHEED

(4)

7 Conclusions

(6)

Acknowledgments

(1)

References

(3)

Further Reading

(2)

2 Sputtering techniques for epitaxial growth of complex oxides

(16)

M. Dawber

1 Introduction

(1)

2 General considerations for sputtering of complex oxides

(5)

3 A practical guide to the sputtered growth of perovskite titanate ferroelectrics

(7)

4 Conclusions

(4)

References

(3)

3 Hybrid oxide molecular beam epitaxy

(22)

Adam P. Kajdos

Nicholas G. Combs

Susanne Stemmer

1 Introduction

(3)

2 Metal-organic precursors for oxide HMBE

(2)

3 Deposition kinetics of binary oxides from MO precursors

(4)

4 Opening a growth window with MO precursors

(3)

5 Properties of materials grown by hybrid oxide MBE

(3)

6 Limitations of HMBE and future developments

(7)

Acknowledgments

(1)

References

(6)

4 Chemical solution deposition of oxide thin films

(26)

Johan E. Ten Elshof

1 Introduction

(2)

2 Reagents and solvents

(2)

3 Types of CSD processes

(4)

4 Film and pattern formation

(5)

5 Crystallization, densification, and epitaxy

(5)

6 Examples of CSD-derived oxide films

(3)

7 Conclusions

(5)

References

(4)

5 Epitaxial growth of superconducting oxides

101

(36)

Hideki Yamamoto

Yoshiharu Krockenberger

Michio Naito

1 Introduction

101

(1)

2 Overview of epitaxial growth of superconducting oxides

102

(1)

3 Requirements for growth of high-quality complex metal-oxide films by molecular-beam epitaxy

103

(3)

4 Case studies

106

(17)

5 Synthesis of new superconductors by thin-film growth methods

123

(3)

6 Conclusions and future trends

126

(1)

7 Sources of further information and advice

126

(11)

Acknowledgments

127

(1)

References

127

(10)

6 Interface-induced effects on the polarization response of epitaxial ferroelectric thin films---an experimental study and theoretical analysis

137

(20)

Evert P. Houwman

Luuk Okkerman

Minh T. Do

Gertjan Koster

Guus Rijnders

1 Introduction

137

(2)

2 Model interface structure and sample description

139

(1)

3 Effects of SRO/PZT interface on ferroelectric properties

140

(12)

4 Discussion and conclusions

152

(5)

References

153

(4)

Part Two

157

(242)

7 Strain engineering during epitaxial growth of oxides

159

(40)

Arturas Vailionis

1 Introduction

159

(1)

2 Crystal structures of perovskites and related oxides

160

(4)

3 Lattice mismatch-induced stress accommodation in oxide thin films

164

(20)

4 Effect of misfit strain-induced distortions on transport and magnetic properties

184

(8)

5 Conclusions and future directions

192

(7)

References

193

(6)

8 Defects in oxide crystals: nanoscale and interfacial effects

199

(32)

Carlos Leon

Jacobo Santamaria

1 Introduction

199

(1)

2 Ion transport in oxide crystals: yttria stabilized zirconia and oxide pyrochlores

200

(7)

3 Space charge effects at grain boundaries

207

(4)

4 Effects of epitaxial strain on ion transport at oxide interfaces

211

(4)

5 Novel functionalities of oxygen vacancies in ferroelectric tunnel junctions

215

(16)

References

221

(10)

9 Interfaces

231

(36)

Zhaoliang Liao

Guanglei Cheng

LingFei Wang

Yanwei Cao

1 Introduction

231

(1)

2 Introduction to oxide interface

232

(2)

3 Interface engineering knobs

234

(14)

4 Manipulation of interface states

248

(10)

5 Conclusions and perspectives

258

(9)

References

259

(8)

10 Stoichiometry in epitaxial oxide thin films

267

(32)

Regina Dittmann

Alessia Sambri

1 Introduction

267

(1)

2 General aspects of stoichiometry transfer in physical vapor deposition techniques

268

(1)

3 Cation stoichiometry transfer during PLD growth

269

(9)

4 Adjustment of the oxygen stoichiometry during PLD growth

278

(3)

5 Accommodation of nonstoichiometry in oxide thin films

281

(5)

6 Impact of nonstoichiometry on oxide thin film properties

286

(4)

7 Future trends

290

(1)

8 Sources of further information

291

(8)

Acknowledgments

292

(1)

References

292

(7)

11 In situ X-ray scattering of epitaxial oxide thin films

299

(32)

H. Zhou

D.D. Fong

1 X-ray toolkits for probing surface/interface: an expanding list

299

(9)

2 Watching surface/interface evolution for epitaxial oxide synthesis

308

(5)

3 Interrogating emergent properties at oxide interfaces

313

(7)

4 Probing functional epitaxial oxide heterostructures for energy harvesting

320

(3)

5 Future perspectives

323

(8)

Acknowledgments

324

(1)

References

325

(6)

12 Scanning probe microscopy of epitaxial oxide thin films

331

(38)

Hangwen Guo

Jiandi Zhang

1 Introduction

331

(1)

2 Basic principles of scanning probe microscopy

332

(4)

3 Scanning probe microscopy studies of CMR manganite thin films

336

(13)

4 Scanning probe microscopy study on ferroelectric and multiferroic thin films

349

(8)

5 Cross-sectional scanning tunneling microscopy, spectroscopy, and electrochemical strain microscopy

357

(1)

6 Projective views on microscopic characterization of epitaxial oxide films

358

(11)

Acknowledgments

358

(1)

References

358

(11)

13 High-resolution transmission electron microscopy and spectroscopy of epitaxial metal oxides

369

(30)

Hongchu Du

Chun-Lin Jia

1 Introduction

369

(1)

2 Transmission electron microscopies and spectroscopies

370

(6)

3 Application of quantitative HRTEM based on NCSI

376

(7)

4 Application of quantitative STEM and spectroscopy

383

(12)

5 Conclusions

395

(4)

Acknowledgments

395

(1)

References

396

(3)

Part Three

399

(104)

14 Optical properties and characterization of oxide thin films and heterostructures

401

(48)

Woo Seok Choi

Ambrose Seo

Changhee Sohn

Ho Nyung Lee

1 Introduction

401

(1)

2 Fundamentals of optical spectroscopy

401

(6)

3 Optical band gap engineering of oxide heterostructures

407

(4)

4 Optical probing of correlated electronic behaviors

411

(12)

5 Evolution of electronic structure in low-dimensional oxides

423

(12)

6 Spectroscopic understanding of electrochemical behaviors

435

(3)

7 Operando spectroscopic characterization

438

(6)

8 Summary and outlook

444

(5)

References

445

(4)

15 High-performance electrostrictor oxide thin films

449

(20)

Simone Santucci

Haiwu Zhang

Nini Pryds

Vincenzo Esposito

1 Introduction into classical electrostriction

449

(4)

2 Applications

453

(1)

3 Nonclassical electrostriction

453

(4)

4 Gd-doped ceria thin films

457

(6)

5 Conclusions and future perspective

463

(6)

References

465

(4)

16 Spintronics: an application of complex metal oxides

469

(34)

M. Bowen

1 Introduction: present stakes for spintronics

469

(1)

2 Magnetic interactions in complex metal oxides

470

(2)

3 Spintronic techniques

472

(5)

4 Complex oxide electrodes for spintronics

477

(7)

5 Spacers with intrinsic functionality

484

(6)

6 Spintronic opportunities at oxide heterointerfaces

490

(1)

7 Conclusions and perspectives

491

(12)

Acknowledgments

492

(1)

References

493

(10)

Index

503

Gertjan Koster is a Professor at the University of Twente in the Netherlands. He is also a visiting professor at the Joseph Stephan Institute in Slovenia. His current research focuses on the growth and study of artificial materials, the physics of reduced scale (nanoscale) materials, metalinsulator transitions, and in situ spectroscopic characterization. Mark Huijben is a Professor at the University of Twente in the Netherlands. He is also a Guest Scientist of the IEK-1 Electrochemical Storage Department at Forschungszentrum Jülich in Germany. His research currently focuses on nanostructured thin films for advanced energy conversion and storage. Guus Rijnders is a Professor and Chairman of Inorganic Materials Science, University of Twente, Enschede, Netherlands. His research currently focuses on the integration of functional and smart materials with electronic and microelectromechanical systems (MEMS).

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